Multielectron redox reactions between manganese porphyrins mediated by nitrogen atom transfer
نویسندگان
چکیده
منابع مشابه
Atom transfer radical cyclisation reactions mediated by copper complexes.
This article describes recent advances in the use of copper complexes in mediating atom transfer radical cyclisation reactions (ATRC). Recent developments have included the design of activated complexes which mediate the cyclisation of tri-, di-, and mono-halo derived substrates at ambient temperatures. Using this methodology, cyclisation to give a variety of ring sizes (4-18 membered rings) ha...
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effects of imidazoles and substituted pyridines and pure s-donors on the oxidation of cyclooctene with naio4 by 5,10,15,20-tetraphenylporphyrinato-manganese(iii) acetate, mn(tpp)oac, and 5,10,15,20-tetramesitylporphyrinato-manganese(iii) acetate, mn(tmp)oac, catalysts in ch2cl2-h2o solvent are studied. coordination of the nitrogen donors to the mn-catalysts generally caused a reduction in the e...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 1989
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja00192a047